离子液抽取剂在增强分离2-propanol-n-hexane azeotrope系统中的应用
Huanxin Li1, Bo Zhu2, Xin Ding1
1School of Biological and Chemical Engineering, Nanyang Institute of Technology, Nanyang, Henan 473004, People's Republic of China.
概括
离子液有效地分离2 - 醇和n - 素亚热类. 氧胺Cl (C8A19) 被确定为一种高性能提取剂,在低度下分解亚热.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 分离科学 分离科学
- 材料科学 材料科学 材料科学
背景情况:
- 2-醇和n-hexane是重要的工业化学品.
- 它们的亚热热组混合物带来了分离的挑战.
- 有效的分离对于各种行业至关重要.
研究的目的:
- 为了确定有效的离子液体,以分离2-propanol-n-hexane azeotrope.
- 用选择性和容量指标评估离子液体.
- 验证预测模型并分析分离机制.
主要方法:
- 使用导体样选模型进行真实解决 (COSMO-RS) 预测模型.
- 根据选择性系数 (S) 和容量 (C) 选了435种离子液体.
- 验证了模型可靠性,并进行了理论和实验研究.
主要成果:
- 鉴定出胺Cl (C8A19) 作为一种优质的离子液体提取剂.
- C8A19成功地将2-propanol-n-hexane azeotrope 在0.02摩尔分数中分解.
- 证实了COSMO-RS模型对该系统的可靠性.
结论:
- 氧胺Cl (C8A19) 是一个有前途的提取剂,用于分解2-propanol-n-hexane azeotrope.
- 这项研究为设计新型离子液提取剂提供了一个框架.
- 微观的分子相互作用解释了选择性机制.
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