关于粘性流的交叉温度与液体中的结构重排有关
Michael I Ojovan1,2, Dmitri V Louzguine-Luzgin2,3
1Department of Materials, Imperial College London, South Kensington Campus, Exhibition Road, London SW7 2AZ, UK.
Materials (Basel, Switzerland)
|March 28, 2024
概括
已确定液体粘性流的新交叉温度,发生在之前已知的过渡温度以上. 这一发现为预测极端温度下液体粘度和流动行为提供了新的方程.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 流体动力学 流体动力学
背景情况:
- 液体粘度通常在较低的温度下表现出非Arrhenius行为,并在较高的温度下转变为Arrhenius行为.
- 一个已知的交叉温度标志着从非Arrhenius到Arrhenius行为的过渡,与最小粘度 (ηmin) 相关.
研究的目的:
- 调查粘性流中的额外交叉存在的情况,温度高于已确定的非Arrhenius到Arrhenius交叉.
- 提出明确的方程来计算这种新的交叉温度 (T) 和可能的最小粘度 (ηmin).
主要方法:
- 液体中粘性流量的理论分析.
- 对T和 ηmin. 的明确方程的开发.
- 数字估计和与实验数据的比较.
主要成果:
- 在明显高于已知的交叉温度时,确定了粘性流量的额外交叉温度 (T).
- 为T和 ηmin提出的方程准确地预测了实验测量的数据.
- 数字估计表明,T几乎是无法达到的,但在这个温度附近可以观察到它的影响.
结论:
- 这项研究揭示了以前未知的液体粘性流中的高温交叉.
- 提出的方程为预测极端热条件下的液体行为提供了有价值的工具.
- 了解这种非激活的流量状态有助于更广泛地了解流体动力学.
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