自然石英的高温反应性湿化由液体
Azam Rasouli1, Artur Kudyba2, Grzegorz Bruzda2
1Department of Materials Science and Engineering, Norwegian University of Science and Technology, 7491 Trondheim, Norway.
Materials (Basel, Switzerland)
|March 28, 2024
概括
石英 (SiO2) 通过液体 (Mg) 的高温湿随着温度的增加显著改善. 在1173K以上,SiO2被Mg完全浸湿,受界面反应的影响.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 表面科学是一门学科.
背景情况:
- 了解高温湿对于材料加工和连接至关重要.
- 的反应性和石英的特性在实现良好的湿方面提出了挑战.
- 上原生氧化物层可以阻碍湿行为.
研究的目的:
- 为了研究天然石英 (SiO2) 通过液态 (Mg) 的高温湿行为.
- 为了确定温度对SiO2/Mg湿系统的影响.
- 在不同温度下分析接口微观结构和反应产物.
主要方法:
- 在973K和1273K之间进行了滴实验.
- 使用毛细血管净化 (CP) 程序从液体Mg中去除原生氧化物层.
- 在阿贡 (Ar) 气体大气层下进行了实验.
主要成果:
- 湿行为强烈依赖温度.
- 在973 K (90°) 和1073 K (65°) 观察到适度的湿.
- 在1123K发生了改善的湿 (22°),在1173K及以上达到完全湿.
- 接口微观结构随温度而变化,表明不同的反应产物.
结论:
- 温度是实现SiO2和Mg之间有效湿化的关键因素.
- 在足够高的温度 (≥1173K) 下,石英可以完全被液态湿.
- 接口反应在观察到的湿现象中起着重要作用.
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