简单的制备纤维素珠,可调整分级孔和高机械强度
Ranjv Meng1,2, Lin Liu2, Xiuping Su3
1School of Fashion Design, Jiaxing Vocational Technical College, Jiaxing 314036, China.
Polymers
|March 28, 2024
概括
研究人员开发了一种新方法来制造具有可调节的多孔结构和提高机械强度的纤维素珠. 这些环保的珠子显示出对先进的分离和吸附应用的前景.
科学领域:
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
背景情况:
- 基于纤维素的多孔珠子由于可生物降解性和生物相容性而有望吸附和分离.
- 现有的制造方法会产生机械性能差,层次结构控制不良的纤维素珠,限制其寿命和细分能力.
研究的目的:
- 开发一种易于制造纤维素珠的方法,具有可调节的层次性多孔结构和增强的机械性能.
- 通过过程优化,系统地调节珠子的宏观大小,微孔结构和机械性能.
主要方法:
- 在纤维素珠制备中采用了一种爬行-掉落方法.
- 优化包括控制注射喷嘴直径,凝结浴组合 (H2SO4-Na2SO4),温度和纤维素度.
- 复合材料浴促进了密集的外和松散的核心结构的形成.
主要成果:
- 该方法允许系统调节珠子的大小,多孔度 (93.38-96.18%) 和球形度 (86.78-94.44%).
- 纤维素珠显示出出色的机械性能,在5%的纤维素度下达到544.24kPa的压力强度.
- 实现了密集的外/松散的核心结构,将高孔隙度与机械强度相结合.
结论:
- 简单的爬行-掉落方法成功地生产了具有可调节的微观结构和优越的机械强度的纤维素珠.
- 这些先进的纤维素珠子具有在废水处理,化学工程,生物工程,医学和制药领域的应用的巨大潜力.
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