通过辐射交叉连接增强低密度和高性能纤维增强PP/POE复合泡
Hongfu Li1, Tianyu Wang1, Changwei Cui1
1School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Polymers
|March 28, 2024
概括
这项研究通过与多烯弹性体 (POE) 混合,交叉连接和添加纤维来增强聚烯 (PP) 泡. 由此产生的复合泡实现了高膨胀率和改进的机械性能,用于先进的材料应用.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 复合材料 复合材料 复合材料
背景情况:
- 半晶体聚烯 (PP) 泡具有较低的融化粘度,导致机械性能差,尽管膨胀比高.
- 现有的PP泡改造往往难以平衡低密度与足够的机械完整性.
研究的目的:
- 开发一种改性聚烯泡,具有增强的机械性能和高膨胀率.
- 研究与聚烯烯弹性体 (POE) 混合,辐射交叉连接和纤维增强对PP泡特性的联合影响.
主要方法:
- 系统地将聚烯 (PP) 与多烯弹性体 (POE) 混合在一起.
- 辐射交叉连接以提高融强度和热稳定性.
- 加入纤维增强 (短碳纤维) 来提高机械性能.
- 优化材料组成和加工条件.
主要成果:
- 实现了一种纤维增强交联PP/POE复合泡,密度低 (0.057g/cm3) 和扩张率高 (16倍).
- 与交联PP/POE系统相比,拉伸强度增加了200% (0.69MPa).
- 观察到冲击强度,抗撕裂和减少热收缩的显著改善.
结论:
- POE混合,辐射交联和纤维增强的协同组合有效地克服了低粘度PP泡的局限性.
- 辐射交联增强了融强度和热稳定性,而纤维增强增强了机械性能.
- 开发的复合泡为低密度,高性能应用提供了有前途的解决方案.
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