热损伤对高能推进剂冲击反应特征的影响
Fengwei Guo1, Jianxin Nie1, Suoshuo Zhang1
1State Key Laboratory of Explosion Science and Safety Protection, Beijing Institute of Technology, Beijing 100081, China.
Polymers
|March 28, 2024
概括
推进剂中的热损伤改变了微观结构,影响了火箭发动机的安全性. 升高的温度会增加孔隙性,并影响引爆的增长,因此需要特定温度的安全模型.
科学领域:
- 材料科学 材料科学 材料科学
- 固体推进剂燃烧 固体推进剂燃烧
- 影响力动态的影响力动态
背景情况:
- 在热刺激下,推进剂的微观结构变化会造成损伤,影响敏感性和燃烧.
- 这种损坏影响了固体推进燃料火箭发动机的整体冲击安全性.
研究的目的:
- 量化分析推进剂在加热过程中的热分解和损伤特征.
- 阐明环境温度对高能推进剂的冲击启动和爆炸增长的影响,在中观层面.
- 提出一种用于校准不同温度下的推进剂反应速率模型的方法.
主要方法:
- 设计了一种统一的加热元件,用于在不同温度下进行拉格朗日和EFP冲击测试.
- 分析了热分解和损伤特征.
- 使用LS-DYNA进行关键外厚度计算.
主要成果:
- 由于热力学损伤,样品的多孔度增加了0.89%,主要是AP和粘合剂之间的界面解接.
- 增加的热损伤改变了热点反应速率,显著影响了冲击启动的增长.
- 校准了20°C和70°C高能推进剂的理论模型参数.
结论:
- 热损伤显著影响推进剂冲击启动和爆炸增长.
- 校准模型为安全评估提供准确的关键外厚度 (20°C时15毫米,70°C时20毫米).
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