聚乙烯,聚乙烯碳酸盐和聚乙烯的合成使用含有有机复合剂的双金属化物催化剂的多
Eun-Gyeong Lee1, Chinh-Hoang Tran1, Ju-Yeong Heo1
1School of Chemical Engineering, Pusan National University, Busandaehag-ro 63-2, Geumjeong-gu, Busan 46241, Republic of Korea.
Polymers
|March 28, 2024
概括
新的 (II) - (III) 双金属化物催化剂与有机复合剂在环开聚合过程中表现出高活性,产生用于块共聚合物和聚乙烯碳酸盐的高级聚合物.
科学领域:
- 协调化学 协调化学
- 聚合物科学 聚合物科学
- 催化剂是一种催化剂.
背景情况:
- 双金属化物 (DMC) 催化剂对于合成聚合物至关重要.
- 有机化合物可以改变催化剂的特性.
- 对于循环单体的受控聚合,需要有效的催化剂.
研究的目的:
- 开发使用有机复合剂的新型Zn(II) -Co(III) DMC催化剂.
- 研究环开放聚合物的催化活性和选择性 (ROP).
- 为先进的聚合物应用合成高质量的聚合物.
主要方法:
- 用有机复合剂合成Zn (II) -Co (III) DMC催化剂.
- 使用红外光谱学,X射线光电子光谱学,元素分析和现场NMR进行表征.
- 评估氧化物和e-caprolactone在ROP中的催化性能,以及与CO2的共聚化.
主要成果:
- 催化剂在氧化物ROP中表现出异常活力 (长达631.4分钟-1分钟) .
- 聚聚的高效合成,适用于生产聚乙烯的triblock共聚合物.
- 在氧化物与二氧化碳的共聚合过程中具有很高的选择性,产生高达34.5%碳酸盐含量的多聚.
结论:
- 有机改性DMC催化剂提供了增强的活性和选择性.
- 开发的催化剂使得能够合成明确定义的多和共聚合物.
- 这项工作推进了生产高性能聚合物的高效催化系统.
相关概念视频
Alkylation of β-Diester Enolates: Malonic Ester Synthesis
3.4K
Malonic ester synthesis is a method to obtain α substituted carboxylic acids from ꞵ-diesters such as diethyl malonate and alkyl halides.
3.4K
Olefin Metathesis Polymerization: Overview
2.1K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
2.1K
Preparation of Epoxides
7.7K
Overview
Epoxides result from alkene oxidation, which can be achieved by a) air, b) peroxy acids, c) hypochlorous acids, and d) halohydrin cyclization.
Epoxidation with Peroxy Acids
Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of...
Epoxides result from alkene oxidation, which can be achieved by a) air, b) peroxy acids, c) hypochlorous acids, and d) halohydrin cyclization.
Epoxidation with Peroxy Acids
Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of...
7.7K
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Ethers from Alcohols: Alcohol Dehydration and Williamson Ether Synthesis
10.3K
Overview
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
Preparation of Ethers by Alcohol Dehydration
In this method, in the presence of protic acids, alcohol dehydrates to produce alkenes and ethers under different conditions. For example, in the presence of sulphuric acid, dehydration of ethanol at 413 K yields ethoxyethane, whereas it yields ethene at 443 K.
10.3K
Esters to Carboxylic Acids: Acid-Catalyzed Hydrolysis
2.8K
Hydrolysis of esters under acidic conditions proceeds through a nucleophilic acyl substitution. In the presence of excess water, the reaction proceeds in a reversible manner, forming carboxylic acids and alcohols.
During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
During hydrolysis, the ester is first activated towards nucleophilic attack through the protonation of the carboxyl oxygen atom by the acid catalyst. The protonation makes the ester carbonyl carbon more electrophilic. In the next step, water acts as a nucleophile and adds to the...
2.8K


