刚果红色染料的降解使用含有Fe的矿物质作为从废弃的造厂灰尘中获得的反应材料
Hyunsoo Kim1, Chulhyun Park1, Nagchoul Choi2
1Department of Energy and Resource Engineering, Chosun University, Gwang-Ju, 61452, Korea.
Environmental science and pollution research international
|March 28, 2024
概括
废造粉尘 (WFD) 有效催化了芬顿氧化过程,以去除刚果红色染料. 来自WFD的铁化驱动基生成,这对污染物降解至关重要.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 工业废物管理 工业废物管理
背景情况:
- 铁基材料对于氧化工业污染物是有效的.
- 废造粉尘 (WFD) 是一种具有作为反应材料潜力的氧化铁.
研究的目的:
- 调查WFD的物理化学特性.
- 评估WFD在芬顿氧化中的可行性,以去除刚果红色 (CR).
- 在过程中评估基 (•OH) 生成和铁溶解.
主要方法:
- 在芬顿氧化过程中利用WFD作为催化剂.
- 在不同的条件下分析了CR降解效率 (H2O2度,pH,WFD剂量,CR度,离子).
- 监控OH生成和铁溶解.
主要成果:
- •OH生成与WFD中的Fe (II) 化有关.
- 随着H2O2和WFD剂量的增加,CR降解效率增加.
- 化物和硫酸盐增强了降解,而碳酸盐抑制了它.
- 由于被动化,降解效率在三个重复使用周期内从100%降至81.1%.
结论:
- 通过芬顿氧化,WFD可以作为通过芬顿氧化去除CR的催化剂.
- 铁氧化还原循环和化是OH生成的关键.
- 表面被动化和铁复合阻碍了长期的催化活性.
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