水凝中的高突破压使得超盐废水的超稳定处理成为可能
Yanni Ma1, Zehua Yu1, Xifan Fu1
1MOE Key Laboratory of Hydraulic Machinery Transients, School of Power and Mechanical Engineering, Wuhan University, Wuhan, Hubei 430072, China.
Nano letters
|March 28, 2024
概括
一种新的水凝层可以防止膜蒸中的污染物引起的膜湿. 这一突破增强了高盐度条件下的稳定性,使有效的废水处理成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 低表面张力污染物会在膜蒸过程中引起湿,特别是在高盐环境中.
- 这种湿现象显著阻碍了膜蒸过程的效率和寿命.
研究的目的:
- 制定消除表面影响和管理蒸发界面污染物的战略.
- 为了提高膜在具有挑战性的高盐条件下的稳定性和性能.
主要方法:
- 将水凝层融入膜表面.
- 在高度盐和表面活性剂溶液中测试膜的稳定性和性能.
- 使用密度函数理论 (DFT) 和分子动力学 (MD) 模拟来理解水凝-表面活性剂相互作用.
主要成果:
- 复合膜在5M盐和8M表面活性剂溶液中表现出了显著的稳定性.
- 在表面活性剂的存在下,突破压达到20bar,显著超过商业疏水膜的性能.
- 模拟证实了水凝-表面活性剂相互作用在缓解表面效应方面的关键作用.
结论:
- 水凝集成的膜有效地抑制了表面的影响,使膜蒸的稳定运行成为可能.
- 这项技术显示出处理含有油和表面活性物质的复杂超废水的巨大潜力.
- 这些发现为先进的水处理和资源回收提供了有希望的解决方案.
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