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相关概念视频

Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.0K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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DC Battery01:21

DC Battery

790
A conductor needs to be a component of a path that creates a closed loop or full circuit to have a continuous current flowing through it. A current starts to flow if an electric field is created inside an isolated conductor that is not part of a full circuit. The conductor quickly develops a net positive charge at one end and a net negative charge at the other. These charges generate an electric field opposite the direction of the applied electric field, which reduces the current. Eventually,...
790
Intermolecular Forces03:13

Intermolecular Forces

58.3K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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混合固态电池中的异离子接口――在不同固体电解质之间的接口处的电流收缩.

Janis K Eckhardt1,2,3, Sascha Kremer1,2, Leonardo Merola1,2

  • 1Institute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, Giessen D-35392, Germany.

ACS applied materials & interfaces
|March 28, 2024
PubMed
概括
此摘要是机器生成的。

混合固态电池需要了解异离子接口. 微结构解析计算揭示了接口形态,而不仅仅是材料属性,显著影响阻抗光谱,复杂化分析.

关键词:
目前的收缩情况.电网建模电气网络建模异离子接口异离子接口混合固态电池是混合固态电池.阻抗光谱法阻抗光谱法固体电解质是一种固体电解质.

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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 计算建模 计算建模

背景情况:

  • 固态电池在液体电解质系统上具有优势.
  • 使用各种固体电解质的混合细胞概念是有希望的,但在接口上面临挑战.
  • 电荷转移动力学和异离子接口的物理接触极大地影响了性能.

研究的目的:

  • 调查接口形态如何影响固体电解质双层中的阻抗响应.
  • 在阻抗光谱中区分几何接口效应和内在材料特性.
  • 为准确的固体电解质接口的电化学表征提供洞察力.

主要方法:

  • 使用微结构解析的电网计算.
  • 分析侧重于具有不同接口特性的均双层系统.
  • 一个实验性氧化硫化物多层案例研究被用于验证.

主要成果:

  • 孔隙接口创建模拟电荷转移过程的几何阻抗签名.
  • 接口上的电流收缩显著影响阻抗响应.
  • 接口电阻和电容对接触面积,分布,孔隙电容和局部导电性敏感.

结论:

  • 接口上的几何效应可能被误解为电化学过程,使阻抗分析复杂化.
  • 准确评估固体电解质材料参数需要仔细考虑接口形态.
  • 这些发现广泛适用于各种电化学系统中的异质连接.