为什么水生科学家应该更频繁地使用硫稳定同位素比率 (34S)
Vincent Raoult1, Alexandra A Phillips2, James Nelson3
1Blue Carbon Lab, School of Life and Environmental Science, Deakin University, VIC, Australia; Marine Ecology Group, School of Natural Sciences, Macquarie University, NSW, Australia.
Chemosphere
|March 31, 2024
概括
包括硫 (δ34S) 的稳定同位素与碳 (δ13C) 和 (δ15N) 一起在生态和考古学研究中提供了更确的结果. 省略硫可以导致不确定的或误导性的发现,突出其对强大的科学发现的重要性.
科学领域:
- 稳定同位素分析在生态学,生理学,生物学和考古学.
- 光稳定同位素在科学研究中的应用.
背景情况:
- 碳 (δ13C) 和 (δ15N) 的稳定同位素通常被使用,通常不包括硫 (δ34S).
- 排除硫同位素可能源于历史成本,时间或仪器仪表的限制.
- 仅仅依靠碳和同位素可以产生不确定的或误导性的结果.
研究的目的:
- 审查实例研究,证明结合硫 (δ34S) 稳定同位素的好处.
- 突出硫同位素数据如何减轻生态和考古研究中的不确定性.
- 倡导将硫作为"默认"同位素与碳和一起加入.
主要方法:
- 审查分析生物主题 (利基,生理学,饮食,运动,生物考古学) 的案例研究,使用和不使用硫同位素.
- 重新分析现有数据,其中包含硫同位素值.
- 硫同位素热量歧视因子 (TDF) 的初步元分析.
主要成果:
- 案例研究表明,排除硫同位素会导致不利的结果,不同的解释或错过的发现.
- 硫同位素分析显示了很小的,但取决于种类的平均热量歧视 (平均-0.4 ± 1.7 ‰ SD).
- 测量技术的进步减少了对硫同位素分析的障碍.
结论:
- 结合硫 (δ34S) 稳定同位素对于强大而确的科学发现至关重要.
- 排除硫同位素限制了生态和考古研究的深度和准确性.
- 稳定的碳,和硫同位素应该被认为是水生科学研究的新默认.
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