铁促进了土原性溶解有机物质在海底潮透沉积物中的保留
Zhe Zhou1,2, Hannelore Waska3, Susann Henkel1
1Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Bremerhaven 27570, Germany.
Environmental science & technology
|April 1, 2024
概括
海洋透沉积物捕获大量的溶解有机物 (DOM),特别是土壤原生和芳香化合物. 这些沉积物中的铁相是保留这种有机物质的关键,有助于其在沿海海洋中埋葬.
科学领域:
- 海洋地球化学 海洋地球化学
- 沿海海洋学 沿海海洋学
- 生物地质化学生物地质化学
背景情况:
- 海洋透沉积物对于沿海生态系统中有机物循环至关重要.
- 这些沉积物在捕获溶解有机物 (DOM) 中的作用仍然不太清楚.
研究的目的:
- 调查海下透沉积物中DOM的丰度和分子组成.
- 为了确定盐度梯度对德国北海DOM特征的影响.
- 为了确定负责这些沉积物中DOM保留的机制.
主要方法:
- 在孔水和浸出沉积物样本中分析DOM丰度和分子公式.
- 使用超纯水 (UPW) 和0.5M HCl用于DOM出,以评估不同的保留机制.
- 检查的DOM组成沿近近海盐度梯度移动.
主要成果:
- 从沉积物固体中出的DOM明显比孔水DOM更丰富 (54±20倍),具有极端的特征.
- 用HCl液使DOM产量翻了一番,表明缩了芳香和富含氧气的化合物,与铁相溶解有关.
- 地下水的DOM成分随着盐度的增加而变化,从芳香化合物转变为不和化合物.
结论:
- 透性沉积物中较差的晶体铁 (Fe) 阶段显著增强了DOM的保留,特别是土生土长和芳香分数.
- 铁是沿海沉积物中陆地有机物重要的中间储存物.
- 这种以Fe为媒介的保留机制可能会加速有机物沉积在沿海海洋中.
相关概念视频
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Corrosion
24.2K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
24.2K
Formation of Complex Ions
23.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.6K
The Sulfur Cycle
44.1K
Sulfur, an important element in the chemical makeup of proteins, is recycled through the atmosphere and aquatic and terrestrial environments. Found in the atmosphere as sulfur dioxide (SO2), sulfur is released by decaying organisms, weathered rocks, geothermal vents, volcanos, and burning fossil fuels. It is deposited into the ecosystem, cycled through the biotic community, and either released back into the atmosphere as gas or deposited in marine sediment for long-term storage and eventual...
44.1K
The Carbon Cycle
37.4K
Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
37.4K
Gravimetry: Inorganic And Organic Precipitating Agents
1.3K
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
1.3K


