灵活的超级电容器具有基于水凝电解质的宽电化学稳定窗口
Zhixian Qi1,2,3, Ruili Ren1,2, Jingwen Hu1,2
1State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin, 300387, China.
Small (Weinheim an der Bergstrasse, Germany)
|April 1, 2024
概括
这项研究引入了一种用于柔性微型超级电容器的新型水凝电解质. 它通过减少自由水的活动来提高能量密度和工作电压,克服温度限制.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水凝电解质为超级电容器提供了灵活性,但存在结和干燥问题,限制了它们的性能.
- 低能量密度是开发微型超级电容器的一个关键挑战.
研究的目的:
- 为了提高灵活的微型超级电容器的工作电压和能量密度.
- 为了提高水凝电解质的热稳定性和性能.
主要方法:
- 通过溶剂交换开发了一种含有N,N'-二甲基形式胺 (DMF) 和NaClO4的藻酸盐/聚烯胺 (SA/PAAM) 水凝电解质.
- 使用水凝电解质和激光诱导石墨烯 (LIG) 的直接粘附制造的微型超级电容器.
主要成果:
- 该SA/PAAM/DMF/NaClO4水凝电解质实现了高离子导电率 (82.1mS cm-1),断裂强度 (563.2kPa) 和宽电压窗口 (3.5V).
- 微型超级电容器的运行电压为2.0V,具体电容为2.41mF cm-2,能量密度为1.34μWh cm-2.
- 这些设备表现出卓越的循环稳定性,灵活性和集成能力.
结论:
- 拟议的战略有效地减少了自由水活动,提高了超级电容器的性能和稳定性.
- 这种灵活的水凝电解质为先进的微型超级电容应用提供了有前途的解决方案.
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