在低度下进行溶解有机碳 (DOC) 分析的建议和良好实践
Delphine Tisserand1, Damien Daval1, Laurent Truche1
1CNRS, IRD, Univ. Gustave Eiffel, ISTerre, Université Grenoble Alpes, Université Savoie Mont Blanc, Grenoble 38000, France.
MethodsX
|April 1, 2024
概括
适当的协议对于准确的低溶解有机碳 (DOC) 测量至关重要. 玻璃瓶,特定的过器和谨慎的处理将自然水样中的污染降到最低.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
背景情况:
- 对于溶解有机碳 (DOC) 的现有ISO协议认证度≥1mgL-1,但许多研究报告较低的值.
- 目前的ISO协议缺乏关于清洁瓶子,过材料和选择低DOC分析的盖子/隔膜的指导.
研究的目的:
- 评估和优化准确测量低溶解有机碳 (DOC) 度 (≤1毫克L-1) 的协议.
- 评估样品容器,过,酸类型和矩阵对DOC测量的影响.
主要方法:
- 评估已被消毒的玻璃瓶 (450-500°C).
- 用超纯水冲洗测试0.45微米的水性聚四乙烯 (PTFE) 膜.
- 对样本存储的HCl酸化的评估.
- 分析硫化物,和对矩阵效应的分析.
- 在不同储存温度 (4°C和-18°C) 下,对 PTFE 斑块的污染进行了调查.
主要成果:
- 清除污染的玻璃瓶,冲洗的PTFE过器和HCl酸化产生了最低的DOC污染.
- 硫化物,和在DOC分析中显示微小的矩阵效应 (≤10%).
- 穿孔的PTFE支柱体在4°C时引起轻微的DOC污染,而在-18°C时则引起严重的污染.
结论:
- 使用特定瓶子,过器和酸化的优化协议对于可靠的低DOC量化至关重要.
- 仔细选择和储存条件至关重要,以防止低DOC水样中的污染.
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