通过使用浮动流表在煤河中分离和回收有价值的碳成分和/金属
Dan Fang1,2,3, Yangchao Xia1,2, Yonggai Li1,3
1State Key Laboratory of Coking Coal Resources Green Exploitation, China University of Mining and Technology, Xuzhou 221116, China.
ACS omega
|April 1, 2024
概括
煤炭,废物,可以经济地用于和回收. 漂浮预丰富有效地将这些有价值的元素从废物中集中起来.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 矿物加工 矿物加工
背景情况:
- 煤 (CG) 是一个重要的工业固体废物. 它含有具有经济价值的 (Li) 和 (Ga) 度. 目前使用CG带来了经济挑战.
- 从CG中有效地回收Li和Ga对于可持续的资源管理和工业应用至关重要. 需要预先缩策略来提高CG利用的经济可行性.
研究的目的:
- 为了研究矿物质成分和和在煤炭中元素的发生. 评估浮动作为和气体回收前缩方法的有效性.
- 为了确定Li和Ga与煤团内的特定矿物质的关联. 优化漂浮过程,以协同分离有价值的元素和杂质.
主要方法:
- 使用X射线衍射 (XRD) 和扫描电子显微镜 (SEM) 的矿物学分析.
- 使用感应合等离子体原子发射光谱法 (ICP-AES) 进行元素组成分析.
- 飞行时间的二次离子质谱 (TOF-SIMS) 用于阐明元素的发生和矿物质的关联.
- 浮动试验采用预抛弃缩-分离-二次浮动策略.
主要成果:
- 煤炭主要由高岩,石英和金岩组成. 和主要与高和其他粘土矿物质有关.
- 观察到Li,Ga和Al2O3和SiO2含量之间存在很强的相关性,这表明它们与高矿物质有关.
- 优化的漂浮过程实现了灰尘杂质和有价值组件的协同分离. 灰含量增加了3%,和的含量略有增加. 含有Li和Ga的矿物质的回收率达到了66.1%.
结论:
- 漂浮是一种经济可行的方法,用于从煤炭中提前丰富和回收和. 了解矿物学和元素关联是优化回收过程的关键.
- 开发的漂浮策略表明了全面利用煤炭的潜力,将废物转化为关键元素的有价值资源.
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