自然/丁复合材料的协同开发,以改善界面粘合和增强吸震能力
Yang Han1,2, Hongbing Zheng1,3, Yingxue Liu1,2
1State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China.
ACS omega
|April 1, 2024
概括
这项研究开发了一种具有较高不和度的新型丁 (IIR),提高了其与天然 (NR) 的兼容性. 增强的复合材料在减震应用中显示出出色的减震性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 机械工程 机械工程
背景情况:
- 天然 (NR) 具有出色的弹性和机械性能,但对于苛刻的应用需要增强的阻尼.
- 高阻尼性,如丁 (IIR),提供优越的阻尼,但由于低不和缓慢的火山化,面临与NR的兼容性问题.
- 优化NR的减震性能对于建筑和运输等行业的先进的减震材料至关重要.
研究的目的:
- 合成一种经过修改的丁 (IIR),增加不和度,以提高与天然 (NR) 的兼容性和并发火山化.
- 调查增强不和对NR/IIR复合材料的界面特性和阻尼性能的影响.
- 评估这些新型复合材料对于减震应用的适用性.
主要方法:
- 使用异二烯和异二烯合成一个具有4-6mol%不和度的丁 (IIR) 变体.
- 使用原子力显微镜 (AFM) 来测量界面区域宽度的兼容性表征.
- 使用动态机械分析 (DMA) 和加工分析 (RPA) 评估阻尼性能,重点关注损耗因子 (tan δ).
主要成果:
- 合成的IIR变体表现出明显更快的固化时间,并使NR与NR同时发生火山化.
- AFM 显示了NR 和 IIR 之间增强的兼容性,接口区域延伸到 1000 nm.
- 复合材料在环境温度下在广泛的频率 (0.25Hz) 和应变 (10200%) 范围内表现出超过0.1的损耗系数 (tan δ).
结论:
- 丁中不和度的增加有效地克服了与天然的兼容性和加工挑战.
- 开发的NR/IIR复合材料具有卓越的阻尼特性,使其在先进的减震应用中非常有前途.
- 这项研究提供了一条可行的途径,通过修改丁来制造高性能阻尼材料.
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