可生物降解PLA塑料的脱聚合和再/再循环.
YingChao Li1, Shuai Wang1, Song Qian1
1College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China.
ACS omega
|April 1, 2024
概括
聚乳酸 (PLA) 的回收面临着挑战. 本综述探讨了化学脱聚合和上循环方法,以改善PLA废物管理和实现闭环循环回收.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 随着塑料垃圾的增加,我们需要可持续的替代品,如可生物降解的塑料.
- 聚乳酸 (PLA) 是领先的可生物降解塑料,但面临着采用障碍.
- 挑战包括高成本,低回收率和不完全降解PLA.
研究的目的:
- 审查当前的聚乳酸 (PLA) 回收方法,重点是化学回收/再循环.
- 要突出最近在化学脱聚合PLA的进步和技术挑战.
- 讨论PLA废物的封闭循环回收和再循环的未来前景.
主要方法:
- 关于聚乳酸 (PLA) 回收策略的综合文献综述.
- 对PLA废物的化学脱聚合技术的分析.
- 评估回收/回收利用途径及其相关挑战.
主要成果:
- 化学回收/再循环为聚乳酸 (PLA) 废物管理提供了显著的优势.
- 各种化学脱聚合方法显示出有前途,但面临技术障碍.
- 目前的方法需要进一步开发,以实现高效和可扩展的PLA回收.
结论:
- 解决聚乳酸 (PLA) 回收挑战对于环境可持续性至关重要.
- 化学脱聚合的进步是使闭环回收和上循环成为可能的关键.
- 需要进一步的研究来克服障碍,并充分发挥PLA回收的潜力.
相关概念视频
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Free-Radical Chain Reaction and Polymerization of Alkenes
7.8K
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
7.8K
Polymer Classification: Architecture
2.7K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.7K
Polymers
35.7K
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
35.7K
Bioremediation
18.3K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.3K
Step-Growth Polymerization: Overview
3.5K
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
Many natural and synthetic polymers are produced by...
3.5K


