基阳极中的活性材料层/薄膜接口的粘合强度
Kazuma Ogata1, Yuto Kasuya1, Xiang Gao2,3
1Department of Precision Mechanics, Faculty of Science and Engineering, Chuo University, Tokyo 1128551, Japan.
ACS applied materials & interfaces
|April 2, 2024
概括
研究人员开发了激光冲击波粘附测试,以测量离子电池阳极材料的强度. 这一创新有助于通过了解材料分层来提高电池的安全性,耐用性和回收率.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 机械工程 机械工程
背景情况:
- 离子电池 (LIB) 是重要的能量存储设备,其中可持续性 (安全性,耐用性,可回收性) 是重点重点.
- LIB阳极板由铜电流收集器上的活性材料组成.
- 来自电流收集器的活性材料分层会导致短路并降低性能,影响制造和回收.
研究的目的:
- 开发和应用新的方法来量化LIB阳极材料的粘合强度和分层行为.
- 为了研究纯Si基活性材料和铜电流收集器之间的界面粘附.
- 为改善电池设计提供有关故障机制的见解.
主要方法:
- 可量化的激光冲击波粘附测试旨在评估界面强度.
- 基于物理的计算模型被用来进一步量化粘附.
- 分析了不同阳极组合的分层行为.
主要成果:
- 激光冲击波测试有效地描述了粘附强度和分层.
- 一个计算模型提供了定量粘附测量.
- 碳- (C-Si) 复合阳极显示出由于粒子异质性引起的应力度增加了对分层的敏感性.
结论:
- 开发的激光冲击波方法提供了一种有前途的方法来评估阳极材料分层.
- 这种技术为设计下一代可持续电池提供了宝贵的工具.
- 了解界面强度对于提高LIB性能,安全性和可回收性至关重要.
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