在金属有机框架膜中通过太赫兹诱导的相位和扩散过渡增强水的透性
Zhi Zhu1, Lei Wang1, Shaojian Yan1
1Key Laboratory of Optical Technology and Instrument for Medicine, Ministry of Education, College of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China.
Physical chemistry chemical physics : PCCP
|April 2, 2024
概括
太赫兹波显著提高了金属有机框架 (MOF) 膜中的水透性. 这种物理方法可以提高水流量达27倍,同时保持离子排放,提供可持续的水处理解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 环境科学 环境科学
背景情况:
- 淡水短缺需要先进的淡水技术.
- 金属有机框架 (MOF) 膜对淡化有希望,但面临透性挑战.
- 目前的MOF增强策略主要依赖于化学修饰.
研究的目的:
- 通过使用太赫兹 (THz) 波来研究MOF膜中水透性的物理增强.
- 探索THz波影响MOF膜中的水运输和离子排斥的机制.
主要方法:
- 用分子动力学模拟来模拟通过MOF膜的水运输.
- 模拟了特拉赫兹波在特定频率 (7.5 ± 1.0 THz) 对水透性的影响.
- 在THz波辐射下评估了离子排斥能力.
主要成果:
- 太赫兹波辐射提高了MOF膜的水透率,高达27倍.
- 在增强的透过程中,有效的离子排斥得到了维持.
- THz波与水的键振动产生共振,增加分子动能,改变相位和扩散行为.
结论:
- 太赫兹波提供了一种新的物理方法,可以显著提高MOF膜的透性,用于淡化水.
- 这些发现表明了有效的水处理和资源可持续性的新途径.
- 响应诱导的相位过渡和改变的扩散动态是THz增强水透的关键.
相关概念视频
Membrane Fluidity
Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.Fatty acids tails of phospholipids can be either saturated or...
Intermolecular Forces
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Metal-Ligand Bonds
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Membrane Fluidity
Membrane fluidity is explained by the fluid mosaic model of the cell membrane, which describes the plasma membrane structure as a mosaic of components—including phospholipids, cholesterol, proteins, and carbohydrates—that gives the membrane a fluid character.
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Mosaic nature of the membrane
The mosaic characteristic of the membrane helps the plasma membrane remain fluid. The integral proteins and lipids exist as separate but loosely-attached molecules in the membrane. The membrane is a relatively...
Extraction: Advanced Methods
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...


