硫化物对DNRA分布和微生物群落结构在硫化物驱动的酸盐减少过程中的作用
Xiaoling Li1, Jianqiang Zhao2, Zhaolin Lu3
1Key Laboratory of Water Supply & Sewage Engineering, Ministry of Housing and Urban-Rural Development, School of Civil Engineering, Chang'an University, Xi'an, 710054, China.
概括
在硫驱动的自脱过程中,与硫化物/酸盐比率的增加一起,分散性酸盐降解为 (DNRA) 成为主导性. 这种微生物过程为增强生物去除提供了见解,特别是在anammox.
科学领域:
- 环境微生物学 环境微生物学
- 生物地质化学循环的过程
- 废水处理 废水处理
背景情况:
- 微生物酸盐降解涉及竞争性脱化 (DEN) 和异型酸盐降解 (DNRA) 途径.
- 了解DNRA在硫驱动过程中的作用对于优化去除至关重要.
研究的目的:
- 调查DNRA在硫驱动的自无化过程中的分布和主导地位.
- 为了确定不同硫化物/酸盐 (S/N) 比率对DNRA患病率的影响.
主要方法:
- 实验室规模的生物膜批量反应器 (SBBR) 测序实验.
- 批量测试采用受控的,增加的S/N比率 (1.5:1, 1.7:1, 2:1).
- 监测氧化降解潜力 (ORP) 和16S rRNA基因测序,用于微生物社区分析.
主要成果:
- 随着S/N比率的增加,DNRA的主导地位增加,在1.5:1比率上达到35.3%.
- 只有SOAD条件下的酸盐/酸盐消费的明显ORP拐点,在DNRA共存时重叠.
- 确定了Ignavibacterium,Hydrogenophaga和Geobacter作为关键的DNRA种类.
结论:
- 在较高的S/N比率下,DNRA成为硫化物氧化自脱 (SOAD) 的重要途径.
- 通过ORP模式和微生物社区分析,可以监测DNRA分歧.
- 结果为改善生物去除提供了洞察力,特别是与anammox过程结合使用.
更多相关视频
相关概念视频
Preparation and Reactions of Sulfides
4.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.8K
Diazonium Group Substitution: –OH and –H
2.8K
Nitrous acid, a weak acid, is prepared in situ via the reaction of sodium nitrite with a strong acid under cold conditions. This nitrous acid prepared in situ reacts with primary arylamines to form arenediazonium salts. Such reactions are known as diazotization reactions. As shown in Figure 1, the formation of arenediazonium salts begins with the decomposition of nitrous acid in an acidic solution to give nitrosonium ions.
2.8K
The Sulfur Cycle
44.1K
Sulfur, an important element in the chemical makeup of proteins, is recycled through the atmosphere and aquatic and terrestrial environments. Found in the atmosphere as sulfur dioxide (SO2), sulfur is released by decaying organisms, weathered rocks, geothermal vents, volcanos, and burning fossil fuels. It is deposited into the ecosystem, cycled through the biotic community, and either released back into the atmosphere as gas or deposited in marine sediment for long-term storage and eventual...
44.1K
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism
3.8K
Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
3.8K
Structure and Nomenclature of Thiols and Sulfides
4.7K
Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
4.7K
Electrophilic Aromatic Substitution: Sulfonation of Benzene
6.0K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
6.0K


