在降雨下,在废弃的炼厂的异质地下地表中,和的迁移
Chao Li1, Yiyuan Ran2, Pan Wu3
1State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China; College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 101408, China.
Journal of hazardous materials
|April 2, 2024
概括
土壤中的反 (Sb) 和 (As) 迁移受到地点异质性的影响. 了解土壤层和化学相互作用对于评估废弃的炼场的风险至关重要.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 土壤科学 土壤科学
背景情况:
- 反 (Sb) 和 (As) 的共同污染是Sb前炼场所的一个已知的问题.
- 地下异质性对Sb和As迁移的影响仍未得到充分研究.
研究的目的:
- 在一个废弃的炼厂的垂直分层,污垢影响的地下地表中调查Sb和As的迁移.
- 确定控制污染物运输和积累的关键因素.
主要方法:
- 作为污染现场的实验室规模模型,使用了2D管道.
- 模拟降雨和停止降雨事件被应用于流水.
- 使用反应式运输建模来解释实验数据.
主要成果:
- 降雨动员了Sb和As从浅层的渣层中,促进了下降运动.
- 较不透的深层土壤阻碍了流动,导致Sb和As在土壤界面积聚.
- 在酸性较深层中重新吸附到氧化铁上进一步减缓了迁移,由于度差异,Sb比As更具流动性.
结论:
- 物理化学异质性显著影响Sb和As的迁移模式.
- 了解这些异质性对于准确的风险评估和污染炼场的有效补救策略至关重要.
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