在没有过渡金属催化剂的情况下,应变的C-C σ-键的长时间反应性

Dachang Bai1,2, Xiuli Guo3, Xinghua Wang4

  • 1State Key Laboratory of Antiviral Drugs, State Key Laboratory of Antiviral Drugs, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Pingyuan Laboratory, Henan Normal University, Xinxiang, 453007, China. baidachang@htu.edu.cn.

Nature communications
|April 2, 2024
PubMed
概括

这项研究引入了一种新型的双循环[1.1.0]butanes (BCBs) 与基的复合反应,在没有金属催化剂的情况下形成C(sp3) -C(sp3) 键. 这扩展了波化学到C-C西格玛键,产生了有价值的环丁和二.

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