pH的基本作用在CH4生物转化为多基酸盐的混合甲类培养中
V Pérez1, R Lebrero1, R Muñoz1
1Institute of Sustainable Processes, Valladolid University, Dr. Mergelina s/n, Spain; Department of Chemical Engineering and Environmental Technology, Valladolid University, Prado de la Magdalena 5, Valladolid, Spain.
Chemosphere
|April 3, 2024
概括
优化pH值是将甲 (CH4) 转化为多基酸盐 (PHAs) 的关键. 较高的pH值提高了CH4的转化率,而较低的pH值增加了特定细菌的PHA积累,这对生物炼油厂至关重要.
科学领域:
- 环境微生物学 环境微生物学
- 生物技术是生物技术.
- 生物精炼是生物精炼的一种方式.
背景情况:
- 气候变化和塑料污染是环境面临的主要挑战.
- 将甲 (CH4) 生物转化为多基酸 (PHAs) 为减轻CH4排放和生产可生物降解的聚合物提供了一种双重解决方案.
- 工业应用需要优化CH4到PHA的生物转化.
研究的目的:
- 研究培养pH对细菌生长,CH4生物转化,PHA积累和微生物群落结构的影响.
- 为了确定最佳的pH条件,以有效地CH4-PHA生物转化在甲类细菌.
主要方法:
- 在乏下在动水箱生物反应器中培养甲型细菌.
- 用不同的pH值 (5.5,7,8.5,10) 进行实验.
- 对CH4生物转化率,PHA积累,生物质生长和细菌群体结构的分析.
主要成果:
- 随着pH值的上升而增加的CH4消除率,在pH值8.5时达到50.4g的CH4·m−3·h−1,可能是由于增强的气液质量转移.
- 在较低的pH值下,聚-3-基酸盐 (PHB) 积聚率更高,在pH值5.5时达到43.7%w·w−1,这归因于Methylocystis等II型甲类动物的选择.
- 持续高的CH4生物降解率48小时后的缺乏,由细胞内PHB积累支持.
结论:
- pH 在CH4-PHA生物转化效率中起着关键和多因素的作用.
- 对于CH4转化率 (性) 和PHA积累 (酸性) 存在不同的pH最佳值.
- 这些发现为优化未来生物炼油厂中CH4生物转化过程提供了关键的见解.
相关概念视频
Mixtures of Acids
681
The pH of a solution containing an acid can be determined using its acid dissociation constant and initial concentration. If a solution contains two different acids, then its pH can be determined using one of several methods depending on the relative strength of the acids and their dissociation constants.
In a strong and weak acid mixture, the strong acid dissociates completely and becomes a source of almost all the hydronium ions present in the solution. In contrast, the weak acid shows...
In a strong and weak acid mixture, the strong acid dissociates completely and becomes a source of almost all the hydronium ions present in the solution. In contrast, the weak acid shows...
681
Bioremediation
18.3K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.3K
Composition of Polyprotic Acid Solutions as a Function of pH
519
Polyprotic acids of the type H2M constitute two ionizable protons. As a result, on titration with a base, they exhibit two equivalence points in the titration curve. During titration, the species H2M, HM−, and M2− will be present in the solution at different points. The fractions of H2M, HM−, and M2− present at the various instances of the titration are denoted by α0, α1, and α2, respectively.
A graph with the alpha values is plotted against the volume of...
A graph with the alpha values is plotted against the volume of...
519
Fates of Pyruvate
8.4K
Pyruvate is the end product of glycolysis, where glucose is oxidized to pyruvate, simultaneously reducing NAD+ to NADH. Two molecules of ATP are also produced by substrate-level phosphorylation.
In aerobic organisms, pyruvate is metabolized via the citric acid cycle to produce reduced coenzymes NADH and FADH2. These coenzymes are then oxidized in the electron transport chain to produce ATP and, in the process, regenerate the NAD+ and FAD. As seen in some cell types and organisms, fermentation...
In aerobic organisms, pyruvate is metabolized via the citric acid cycle to produce reduced coenzymes NADH and FADH2. These coenzymes are then oxidized in the electron transport chain to produce ATP and, in the process, regenerate the NAD+ and FAD. As seen in some cell types and organisms, fermentation...
8.4K
Polyprotic Acids
29.1K
Acids are classified by the number of protons per molecule that they can give up in a reaction. Acids such as HCl, HNO3, and HCN that contain one ionizable hydrogen atom in each molecule are called monoprotic acids. Their reactions with water are:
29.1K


