基于等离子图像频谱融合的等离子素参数校正方法,用于消除LIBS中的矩阵效应
Optics express
|April 4, 2024
概括
这项研究引入了使用等离子体图像频谱融合 (PPC-PISF) 的等离子体参数校正方法,以消除激光诱导分解光谱 (LIBS) 中的矩阵效应. 该方法显著提高了校准曲线的准确性,并减少了各种样本类型的错误.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 材料科学 材料科学 材料科学
背景情况:
- 矩阵效应是激光诱导分解光谱学 (LIBS) 的一个重大挑战,阻碍了其广泛应用.
- 在LIBS中,准确的定量分析往往因样本组成和物理性质的变化而受到损害.
研究的目的:
- 开发和验证一种用于减轻LIBS.中的矩阵效应的新方法.
- 通过改进血表征来提高LIBS分析的准确性和可靠性.
主要方法:
- 提出了基于等离子体图像频谱融合 (PPC-PISF) 的等离子体参数校正方法.
- 利用等离子图像和光谱的有效特征来纠正总数密度,等离子温度和电子数密度的变化.
- 在压制和金属样品上进行实验,将结果与图像辅助LIBS (IA-LIBS) 进行比较.
主要成果:
- 对于压缩样品,与IA-LIBS相比,PPC-PISF提高了R2至>0.993,平均RMSE降低了41.05%,平均ARE降低了59.35%.
- 对于金属样品,与IA-LIBS相比,PPC-PISF将R2增加到>0.997,平均RMSE降低了29.63%,平均ARE降低了38.74%.
结论:
- PPC-PISF方法有效地消除了LIBS.中的矩阵效应.
- 这一进步促进了LIBS技术的进一步发展和工业应用.
相关概念视频
Atomic Emission Spectroscopy: Lab
161
AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
161
Inductively Coupled Plasma-Mass Spectrometry (ICP-MS): Interferences
458
Inductively coupled plasma–mass spectrometry (ICP–MS) is a highly selective and sensitive technique for accurate elemental analysis. Though the analysis of ICP–MS mass spectra is comparatively straightforward, it is affected by spectroscopic and non-spectroscopic interferences. Spectroscopic interferences arise when the plasma contains ionic species with an m/z value the same as the analyte ion. Spectroscopic interference can be categorized as isobaric, polyatomic ions, and...
458
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation
215
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
215
Inductively Coupled Plasma Atomic Emission Spectroscopy: Principle
604
Inductively coupled plasma (ICP) is the most widely used plasma source in atomic emission spectroscopy (AES), also known as Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). The ICP source, or torch, consists of three concentric quartz tubes with argon gas flowing through them. A spark from a Tesla coil initiates the ionization of argon, generating a high-temperature plasma.
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
604
Inductively Coupled Plasma–Mass Spectrometry (ICP–MS): Overview
730
In inductively coupled plasma–mass spectrometry (ICP–MS), an inductively coupled plasma (ICP) torch is used as an atomizer and ionizer. Solid samples are dissolved and volatilized before being introduced into the high-temperature argon plasma, while solution samples are nebulized and passed through the high-temperature argon plasma. Plasma dissociates the analytes and ionizes their component atoms to form a mixture of positive ions and molecular species. The positive ions are then...
730
Atomic Emission Spectroscopy: Interference
183
In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
183


