的腐蚀被动化法规延长了水性电池的使用寿命
Binghang Liu1,2,3, Tianshi Lv1,2,3, Anxing Zhou1,2,3
1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Science, 100190, Beijing, China.
Nature communications
|April 4, 2024
概括
研究人员开发了新的添加剂,以防止水性电池中的腐蚀,显著延长电池寿命. 这一创新使得在水系统中能够使用经济高效的电流采集器.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 电流采集器具有成本效益,但在水性电解质中腐蚀.
- 这种腐蚀限制了它们在水性电池中的使用,阻碍了开发.
研究的目的:
- 开发一种方法来抑制水性电池中的腐蚀.
- 为了提高水性离子电池的循环寿命.
主要方法:
- 引入水解类型的阳极添加剂,以形成一种被动化层.
- 开发了一种原型的水性离子电池 (离子电池) 的原型 (离子电池).
- 使用牺牲性电极作为电子补充剂.
主要成果:
- 的腐蚀电流密度减少了三个数量级 (~10^-6 A cm^-2).
- 在200个循环后,原型水性电池的容量保留率从49.5%提高到70.1%.
- 通过解决电流收集器腐蚀和损失,延长水性电池的循环寿命.
结论:
- 水解类型的阳添加剂有效地抑制水性电解质中的腐蚀.
- 牺牲性电极可以延长水性电池的寿命.
- 这种方法可以在水性电池系统中使用电流采集器.
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