为高性能离子电池开发一种异常高Na含量的P2型分层氧化物阴极,具有接近零应变的强度
Hai-Yan Hu1,2, Jia-Yang Li2, Yi-Feng Liu2
1Institute for Carbon Neutralization, College of Chemistry and Materials Engineering, Wenzhou University Wenzhou 325035 P. R. China yanfangzhu@wzu.edu.cn xiaoyao@wzu.edu.cn.
Chemical science
|April 5, 2024
概括
研究人员开发了一种用于离子电池 (SIB) 的新型P2型分层氧化物阴极. 这种材料在循环过程中保持结构稳定性和高容量,提供更好的电池性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 层状过渡金属氧化物 (NaTMO2) 由于其高容量和导电性,是离子电池 (SIB) 的有希望的阴极材料.
- 然而,它们的电化学性能通常受到循环过程中的相位转换和离子排序的限制.
研究的目的:
- 为SIBs开发一种具有增强结构稳定性和电化学性能的新型阴极材料.
- 研究新材料的储存机制和结构演变.
主要方法:
- 合成一种新的P2型分层氧化物阴极材料.
- 电化学表征包括循环性能和速率能力测试.
- 在现场进行X射线衍射,研究循环过程中的结构变化.
主要成果:
- 这种新型的正极材料表现出一种异常的P2型结构,含有高Na含量.
- 它在0.2C时提供108mA hg-1的可逆容量,在2C时提供97mA hg-1的可逆容量.
- 该材料表现出极好的循环稳定性 (在200个循环后保持76.15%) 和由于固体溶液反应而导致的0.8%的低体积变化.
结论:
- 开发的P2型分层氧化物表现出接近零应变的特征,导致高度稳定的晶体结构用于储存.
- 这种方法为设计用于离子电池的高性能阴极材料提供了一个有希望的策略.
更多相关视频
相关概念视频
Ionic Crystal Structures
14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K
Ionic Bonding and Electron Transfer
41.5K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.5K


