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Updated: Jun 29, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

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无化物CO2循环添加到 styrene 氧化物上,由第一排过渡金属衍生物催化,由多氧化物合物

Jingjing Ren1, Anna Proust1, Franck Launay2

  • 1Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, Sorbonne Université, Campus Pierre et Marie Curie, 4 Place Jussieu, Paris F-75005, France. richard.villanneau@sorbonne-universite.fr.

Chemical communications (Cambridge, England)
|April 5, 2024
PubMed
概括

基于金属的多氧金属酸盐作为四级盐催化剂,有效地将二氧化碳和氧化物转化为碳酸盐. 这种更绿色的催化方法在适度条件下实现了高产量.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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