电化学E-选择性半导体脱碳化阿里尔基与CO2的二氧化碳

Lan Zhao1, Wen-Jun Xie1, Zheng-Zheng Meng1

  • 1State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 30007, P. R. China.

Organic letters
|April 5, 2024
PubMed
概括

这项研究介绍了一种电化学方法,将烯和二氧化碳 (CO) 转化为有价值的布丁二氧化酸. 高效的工艺为有机合成应用提供了高选择性和可扩展性.

相关概念视频

Cycloaddition Reactions: Overview01:16

Cycloaddition Reactions: Overview

Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
2.6K
Carboxylic Acids to Methylesters: Alkylation using Diazomethane01:33

Carboxylic Acids to Methylesters: Alkylation using Diazomethane

Carboxylic acids react with diazomethane in an ether solvent via alkylation at the carboxylate oxygen atom to give methyl esters of the corresponding acid with excellent yields.
2.2K