在河水监测-消化中的未过样本的多元件分析和67个元素的单次分析
Nadine Belkouteb1, Henning Schroeder1, Jan G Wiederhold1
1Division G - Qualitative Hydrology, Federal Institute of Hydrology, Am Mainzer Tor 1, 56068, Koblenz, Germany.
Analytical and bioanalytical chemistry
|April 5, 2024
概括
本研究介绍了在未过的河水中分析无机元素的消化方案. 这种方法通过分析一个样本中的所有分数来简化常规水质监测.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 水质监测 水质监测
背景情况:
- 在整个河水 (未过) 中对无机分析物的分析在科学文献中不足.
- 整体水样本整合了溶解,合体和颗粒物分数,这对于长期监测和元素预算至关重要.
- 目前的方法往往不包括颗粒物,限制了全面的环境评估.
研究的目的:
- 开发和验证消化协议,用于对整个河水进行全面的无机多元元素分析.
- 建立一个简化,自动化的方法,用于日常水质监测.
- 由于缺乏认证的参考材料,采用模拟的全水样本引入质量控制措施.
主要方法:
- 开发了几个针对整个河水样本量身定制的消化方案.
- 用先进的分析技术对67种主要,次要和微量元素进行多元元素分析.
- 创建和利用模拟的全水样本 (悬浮沉积物参考材料) 进行质量控制.
主要成果:
- 成功实施了消化方案,使得整个河水中广泛的无机分析物的分析成为可能.
- 在不同河流环境中用于常规水质监测的应用性.
- 随着时间的推移,观察到元素"指纹"的显著变化,突出了动态的河流过程.
结论:
- 开发的方法简化了对整个河水的分析,消除了对保存的需求,不考虑固体-液体分区.
- 这种方法提高了常规水质监测计划的效率和范围.
- 该研究为了解河流元素动态和改进环境评估提供了一个强大的框架.
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