稀土元素对粘土矿物质的吸附:从二次来源回收的机械洞察和影响
Brendan A Bishop1, Md Samrat Alam2, Shannon L Flynn3
1Department of Geology, University of Regina, 3737 Wascana Parkway, Regina, Saskatchewan S4S 0A2, Canada.
Environmental science & technology
|April 8, 2024
概括
像伊利特和考利尼特这样的粘土显著影响稀土元素 (REE) 运输和沉积在沉积系统中的沉积. 了解REE对这些矿物质的吸附对于资源回收和环境管理至关重要.
科学领域:
- 地质化学 地质化学
- 环境科学 环境科学
- 矿物学是什么?矿物学是什么?
背景情况:
- 能源转型需要像稀土元素 (REE) 这样的关键金属.
- 在水和沉积环境中的二次来源正在引起REE回收的兴趣.
- 粘土矿物质在这些环境中的REE行为中的作用尚不清楚.
研究的目的:
- 为了研究稀土元素 (REE) 吸附在伊利特和高利尼特上的情况.
- 为了确定pH值和离子强度对REE吸附的影响.
- 开发一个表面复杂化模型来预测REE物种化.
主要方法:
- 在不同的pH值和离子强度上进行批量吸附实验.
- 扩展的X射线吸收细结构 (EXAFS) 光谱学.
- 表面复杂化建模.表面复杂化建模.
主要成果:
- 在酸性pH值和高离子强度下,吸附率下降.
- 伊利特的REE吸附能力高于考利尼特.
- 超过95%的REE吸附率在pH值~7.5时实现,不论离子强度或粘土类型.
- EXAFS揭示了REE存在于粘土上的内部和外部球体复合体.
结论:
- 粘土在控制REE运输和沉积系统中的缩方面发挥着重要作用.
- 粘土在REE行为中的重要性随着pH值的上升而增加.
- 发现有助于确定用于REE资源开采的地点,并预测污染物的命运.
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