机械化学启用的转基因稳定氧化
Basirat Raji-Adefila1, You Wang1, Yong Ding2
1Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131, United States.
Journal of the American Chemical Society
|April 9, 2024
概括
机械化学使得具有无序结构的新型转移稳定的氧化物 (NbWO) 成为可能. 这些材料在用作离子电池阳极时表现出独特的转化为阴离子无序立方相.
科学领域:
- 固态化学
- 材料科学
- 电化学
背景情况:
- 超稳定的化合物显著扩大了可访问的材料组成.
- 机械化学对于合成有离子失序的材料,特别是岩盐结构是有效的.
- 转移不稳定的非密集结构的合成仍未得到充分研究.
研究的目的:
- 开发一种新型的氧化物 (NbWO).
- 研究离子失序NbWO结构的合成.
- 在电化学应用过程中探索NbWOs的结构变化.
主要方法:
- 转化稳定的氧化的机械化学合成.
- 包括衍射,电子和振动光谱在内的物理化学表征.
- 作为离子电池阳极的电化学测试.
主要成果:
- 一种具有完全离子结构的新型转移稳定的NbWO的成功合成.
- 在离子电池阳极运行过程中观察到元稳定的NbWO转化为离子无序的立方结构.
- 展示非密封到密封的结构转换.
结论:
- 可以合成转基因稳定的NbWO,包括完全离子失序的变体.
- 当作为离子电池阳极使用时,NbWO会经历独特的结构转换.
- 确定了阴离子乱的主要特征,并提出了未来的研究方向.
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