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Updated: Jun 29, 2025

Spatial Separation of Molecular Conformers and Clusters
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溶剂和质子状态对[s]-Triazines中的旋转障碍物的影响

Liam E Claton1, Hongjun Pan2, Eric E Simanek1

  • 1Department of Chemistry & Biochemistry, Texas Christian University, Fort Worth, Texas 76109, United States.

The Journal of organic chemistry
|April 9, 2024
PubMed
概括

质子化增加了氨基替代三中三-N键周围的旋转屏障 (ΔG‡),在较低的介电溶剂中观察到更高的屏障. 这种阻碍旋转受到溶剂极性和质子状态的影响.

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