精确定义的支持ZnO物种:合成,结构和催化性能在C3-C4基的非氧化脱中
Shanlei Han1, Dan Zhao1, Evgenii V Kondratenko1
1Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
支持的氧化 (ZnO) 物种是和异布坦脱的关键,产生必要的烯酸. 催化剂结构决定了性能,较小的ZnO集群显示出比纳米粒子更高的活性和选择性.
科学领域:
- 不同质的催化剂.
- 材料科学是一种材料科学.
- 化学工程是化学工程的组成部分.
背景情况:
- 氧化 (ZnO) 是一种多功能材料,在各种领域都有应用.
- 支持的ZnO物种越来越多地研究了 (PDH) 和异 (iBDH) 的非氧化脱.
- 了解这些反应中ZnO物种的结构-活性-选择性关系至关重要,但由于制备困难而具有挑战性.
研究的目的:
- 研究不同结构的ZnO物种在PDH和iBDH中的性能.
- 开发可控制备受支持的ZnO物种的方法.
- 为这些催化系统建立结构-活动-选择性关系.
主要方法:
- 使用Zn原子的现场反应,单热水合成,浸/定等方法,对支持的ZnO物种进行量身定制的制备.
- 使用补充的ex/in situ技术对ZnO物种进行表征.
- 动力学研究以确定内在活动和选择性.
主要成果:
- 在基于SiO2和ZrO2的支架上,控制合成ZnO物种,从孤立的原子到纳米粒子.
- ZnO物种的内在活性随着集群大小增加到~10个原子,然后减少纳米粒子.
- 较小的ZnO集群 (隔离到亚纳米) 与纳米颗粒相比,对烯酸具有更高的选择性,这促进了不必要的C1-C2碳化合物和焦炭.
结论:
- 支持的ZnO的物种化显著影响其在PDH和iBDH中的催化性能.
- 精确定义的小ZnO集群为烯酸生产提供了更高的选择性.
- 这项研究为设计高效的基于ZnO的催化剂的C-H键激活反应提供了基本的见解.
更多相关视频
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
08:13Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
Published on: February 19, 2018
相关概念视频
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Catalysis
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Oxidative Cleavage of Alkenes: Ozonolysis
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
