工程含硫聚合物阻燃涂层用于防火固态聚氨泡
Yang Fang1, Zhewen Ma2, Dewang Wei1
1College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou, 311300, China.
Macromolecular rapid communications
|April 9, 2024
概括
新的硫基阻燃共聚合物为聚合物泡提供了增强的消防安全. 聚乙烯硫酸-co-2-基乙烯酸) 涂层显著提高了聚氨泡的耐火性和粘附性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 消防安全工程 消防安全工程
背景情况:
- 聚合物泡是必不可少的热绝缘体,但会带来火灾风险.
- 阻燃涂层对于提高泡防火安全而不会损害其性能至关重要.
研究的目的:
- 合成基于硫的新型阻燃共聚合物.
- 为聚合物泡开发有效的水性涂层.
- 为了评估涂层泡的阻燃性能和粘附性.
主要方法:
- 含硫单体 (SPS,VS,VSS) 与HEA或4-基乙烯酸盐的激进共聚化.
- 在聚氨泡 (PUF) 上涂上600微米的水性阻燃涂层.
- 垂直燃烧试验和限制氧指数 (LOI) 测量以评估阻燃性.
主要成果:
- 涂层PUF获得了V-0评级和LOI>31.5体积%.
- 聚 ((VS-co-HEA) 涂层的PUF显示出优越的接口粘附性和阻燃性.
- 性能最好的涂层表现出166kW m-2的峰值热释放率和36.4%的LOI.
结论:
- 基于硫的共聚合物有效地提高了聚合物泡的消防安全性.
- 聚 ((VS-co-HEA) 涂层提供了出色的阻燃性和粘附性.
- 这项研究为设计先进的阻燃聚合物涂层提供了一条途径.
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