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Updated: Jun 28, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
09:12

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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光诱导C ((sp3) -H自旋化通过电子捐赠-接受复杂介导的化学选择性三组分激素继电器实现

Xiaobo Dang1, Zhixuan Li1, Jinlong Shang1

  • 1Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, 199 West Donggang Road, Lanzhou, 730000, China.

Angewandte Chemie (International ed. in English)
|April 10, 2024
PubMed
概括

这项研究引入了一种新型的三组分反应,用于合成非自然氨基酸,使用电子捐赠体-接受体 (EDA) 复合体和[1.1.1]propellane. 这种方法可以在温和条件下与双环[1.1.1]坦 (BCP) 基组进行直接的C(sp3) -H功能化.

关键词:
在C(sp3)−H功能化过程中.双自行车[1.1.1]坦电子捐赠体接受体复合体激进继电器的继电器

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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization12:19

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