从有机颜料中提取的碳主体的结构工程,用于物理化学封闭和有效地转换聚硫化物,用于硫电池
Woo Sub Heo1, Woong Kwon2, Taewoong Lee1,3
1School of Chemical Engineering, Pusan National University, 2, Busandaehak-ro 63beon-gil, Geumjeong-gu, Busan, 46241, Republic of Korea.
Small methods
|April 11, 2024
概括
研究人员开发了一种使用有机颜料的新型活性碳宿主,以减轻聚硫化物 (LiPSs) 在硫电池 (LSBs) 中的穿效应. 这种结构工程增强了循环稳定性和硫利用,以更好地储存能量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫电池 (LSB) 是下一代储能系统的前景.
- 商业可行性受到多硫化物 (LiPSs) 穿效应的阻碍,导致循环稳定性差,硫利用率低.
研究的目的:
- 开发一种硫宿主,减轻LSB中的LiPSs穿效应.
- 调查结构工程在碳宿主中的作用,以改善LiPSs封闭和电化学性能.
主要方法:
- 通过使用有机颜料的一步激活,制备具有超高表面积的微型/半孔丰富活性碳材料.
- 通过改变化学剂的比例来操纵毛孔大小和体积.
- 电化学测量和光谱分析以评估性能和理解机制.
主要成果:
- 碳宿主的结构工程有效地限制了LiPSs,减轻了穿效应并改善了硫的利用.
- 有机色素中的含和含氧的功能组作为电催化位点,加速LiPSs的转化动力学.
- 设计的碳微结构增强了LiPS的捕获和抑制,显著提高了LSB的电化学性能.
结论:
- 碳微结构的合理设计对于克服LSB中的LiPSs穿效应至关重要.
- 开发的活性碳材料为提高硫电池的稳定性和效率提供了可行的策略.
相关概念视频
Precipitation and Co-precipitation
4.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
4.8K
Coagulation
1.5K
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
1.5K
Extraction: Advanced Methods
1.3K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.3K
Gravimetry: Inorganic And Organic Precipitating Agents
5.9K
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
5.9K
Carbonation Shrinkage
662
Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
662
Carbon-dioxide Fixation
873
Carbon dioxide fixation in prokaryotes enables the assimilation of inorganic carbon into organic molecules, supporting biosynthetic pathways, sustaining ecosystems, and contributing to the global carbon cycle. It also has industrial applications in carbon capture and bioproduct synthesis. Autotrophic organisms rely on this process to utilize CO₂ as a carbon source in diverse environments.The Calvin CycleThe Calvin cycle is the most widespread carbon fixation mechanism, primarily used by...
873


