分子分支和表面湿度对液态烯表面纳米滴的固体-液体表面张力和线张力的影响
1School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006, Australia; Sydney Nano Institute, The University of Sydney, NSW 2006, Australia.
Journal of colloid and interface science
|April 11, 2024
概括
分子分支显著影响基纳米滴的湿行为,影响固体-液体表面张力和线张力. 与线性基相比,分支基表现出较低的线张力,影响方程的有效性.
科学领域:
- 表面科学是一门科学.
- 物理化学 物理化学
- 材料科学是一种材料科学.
背景情况:
- 表面纳米滴的接触角度偏离了方程.
- 线张力 (τ) 是修改方程的一个关键因素,报告的值差异很大.
- 在基中分子分支会影响液体-蒸汽表面张力 (γlv).
研究的目的:
- 调查分子分支对基纳米滴滴湿行为的影响.
- 检查扬方程对不同表面上的线性和分支基的有效性.
- 确定分支对固体-液体表面张力 (γsl) 和线张力 (τ) 的影响.
主要方法:
- 线性 (triacontane) 和分支的基纳米滴的分子动力学 (MD) 模拟 (大约. 15纳米直径的).
- 在油性和油性表面的模拟.
- 确定固体-液体表面张力 (γsl) 和线张力 (τ) 的新方法.
主要成果:
- 计算的γsl偏离了方程对所有基在油性表面上的预测.
- 偏差在油表面的分支基中是最小的,但在线性基中显著.
- 线张力 (τ) 对油性表面是正的,对油性表面是负的,分支基呈现较低或微不足道的 τ 值,特别是在较大的接触角度.
结论:
- 分子分支显著影响基纳米滴的湿性质.
- 扬方程需要修改,而线张力对于准确的预测至关重要.
- 该研究提供了关于表面纳米滴的行为,与技术应用相关的见解.
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