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Updated: Jun 28, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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CF3集团作为Palladium化学中的CF+单元的一个synthon

Daniel Joven-Sancho1, Miguel Baya1, Antonio Martín1

  • 1Instituto de Síntesis Química y Catálisis Homogénea (iSQCH), CSIC-Universidad de Zaragoza, Zaragoza, 50009, Spain.

Angewandte Chemie (International ed. in English)
|April 12, 2024
PubMed
概括

一种新型的复合物,[Pd(CF3)4]2-,与氨基发生反应,形成新的异化物和氨基化合物复合物. 这种前所未有的方法在温和条件下利用三甲基作为N-异环碳合成的前碳单位.

关键词:
在C-F激活过程中.氨基化的氨基化.二碳化合物二碳化合物胺氨基碳化合物胺氨基碳化合物器官帕拉迪乌姆 (organopalladium) 是一种有机物.

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