第二层N剂在孤立的Pt位点调节酸性O2降低通路
Baoxin Ni1,2, Peng Shen2, Guiru Zhang2
1National Key Laboratory of Advanced Micro and Nano Manufacture Technology, Department of Micro/Nano Electronics, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Journal of the American Chemical Society
|April 12, 2024
概括
--碳单原子催化剂中的补剂精确地控制氧降解反应 (ORR) 路径. 这项研究针对燃料电池至关重要的高效能源转化进行了选择性调整.
科学领域:
- 电化学
- 材料科学
- 催化剂
背景情况:
- (Pt) 是酸性氧降解反应 (ORR) 的基准催化剂,对于能量转化至关重要.
- 由于复杂的协调环境,控制单原子催化剂的ORR路径具有挑战性.
研究的目的:
- 研究邻近的 (N) 剂如何影响Pt单个原子的电子结构.
- 在Pt-N-C SAC中证明ORR选择性的调整 (O2-to-H2O与O2-to-H2O2).
主要方法:
- 碳纳米管合成支持Pt-N-C单原子催化剂.
- 使用X射线辐射光谱和隔离纳米粒子增强的拉曼光谱.
- 使用理论建模进行综合分析.
主要成果:
- 通过改变N dopant协调,在0.3V时实现可调节的O2到H2O2选择性从10%到85%.
- 氧化和氧化协调有利于4电子ORR路径.
- 第二层石墨-N引入削弱了*OOH结合,促进了2电子ORR通路.
结论:
- 当地的化学环境,特别是N dopant协调,对于引导Pt SAC中的ORR选择性至关重要.
- 通过操纵单原子催化剂的协调球来精确控制电化学性能.
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