甲基-2-罗利侵蚀对不同等级煤的表面功能组和孔径演变的影响
Wenbo Lv1, Hao Zhang1, Cunbao Deng1
1College of Safety & Emergency Management Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
ACS omega
|April 15, 2024
概括
N-甲基-2-pyrrolidone (NMP) 通过改变煤的功能群和孔隙结构来增强煤床甲的产量. 它的有效性随着煤炭等级的提高而下降,煤和煤显示出明显的孔隙性改善.
科学领域:
- 地质化学 地质化学
- 石油工程是石油工程中的一个.
- 材料科学 材料科学 材料科学
背景情况:
- 低透性煤矿库对甲开采构成了挑战.
- 像N-甲基-2-pyrrolidone (NMP) 这样的有机溶剂显示出改善煤炭性能的潜力.
- 对于NMP对煤炭功能群和孔隙结构的影响机制需要进一步阐明.
研究的目的:
- 调查NMP处理对煤,煤和炭灰矿的功能群和孔隙结构的影响.
- 阐明NMP改变煤炭性质的机制.
- 评估煤炭等级和NMP有效性之间的关系.
主要方法:
- 福里埃变换红外光谱法 (FTIR) 用于分析煤炭功能组的变化.
- 低场核磁共振 (LF-NMR) 用于表征孔隙结构的修改.
- 三个煤层 (煤炭,矿和炭化石) 接受了为期6小时的NMP处理.
主要成果:
- NMP处理增加了含有氧的功能组和芳香度,特别是在煤中.
- 在暴露于NMP后,基和酸碳化合物含量下降.
- 在煤 (84.82%) 和煤 (43.56%) 中,孔隙性显著增加,但在炭酸盐 (3.04%) 中,孔隙性最小.
结论:
- NMP可以选择性地溶解有机分子,增强毛孔连接性,促进微毛孔,中毛孔和巨毛孔的发展.
- 在修改煤炭孔状结构方面,NMP的有效性随着煤炭等级的提高而下降.
- 通过改善煤炭储属性,NMP显示出增强煤床甲生产的潜力.
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