通过电透析转基因分析清洁生产化的过程
Xu Li1, Xinlai Wei1, Ningning Yang1
1School of Biology, Food and Environment, Hefei University, Hefei 230601, China.
ACS omega
|April 15, 2024
概括
电透析转化提供了一种更安全,更有效的生产酸的方法,避免了危险的酸. 这种技术实现了高纯度的化,降低了能源消耗和环境影响.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
背景情况:
- 酸对于电池和药品至关重要.
- 目前使用酸的中和方法由于不稳定性,潜在的爆炸和有毒蒸汽生成而具有危险性.
- 这些限制阻碍了工业规模的化生产.
研究的目的:
- 评估电透析转化作为化生产的可行替代方案.
- 为了研究膜堆配置,工作电压和反应剂度/比率对过程的影响.
- 为了确定通过电透析生产的化的纯度和成本效益.
主要方法:
- 使用特定的膜堆配置 (C-C-A-C-A-C) 的电透析转化.
- 优化工作电压 (25V) 和反应剂参数 (化0.4mol/L,硫酸0.2mol/L,1:1体积比).
- 对产品纯度和生产成本的分析.
主要成果:
- 达到98.9%的高酸纯度.
- 确定生产成本大约为0.502美元/公斤LiI.
- 与传统方法相比,电透析证明了更简单的工艺流程和更低的能源消耗.
结论:
- 电透析转化是一种有效且对环境有益的盐生产和净化技术.
- 优化的电透析过程提供了更安全,更具成本效益的高纯度酸的途径.
- 这种方法克服了与酸生产相关的安全和环境缺点.
相关概念视频
Electrolysis
26.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.3K
Ion-Exchange Chromatography
458
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
458
Extraction: Advanced Methods
446
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
446
Precipitation of Ions
27.9K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
27.9K
Electrodeposition
633
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
633
Esters to Alcohols: Hydride Reductions
3.5K
Esters are reduced to primary alcohols when treated with a strong reducing agent like lithium aluminum hydride. The reaction requires two equivalents of the reducing agent and proceeds via an aldehyde intermediate.
Lithium aluminum hydride is a source of hydride ions and functions as a nucleophile. The mechanism proceeds in three steps. Firstly, the nucleophilic hydride ion attacks the carbonyl carbon of the ester to form a tetrahedral intermediate. Subsequently, the carbonyl group re-forms,...
Lithium aluminum hydride is a source of hydride ions and functions as a nucleophile. The mechanism proceeds in three steps. Firstly, the nucleophilic hydride ion attacks the carbonyl carbon of the ester to form a tetrahedral intermediate. Subsequently, the carbonyl group re-forms,...
3.5K


