揭示了在-40°C下运行的离子电池电压振荡的起源
Lanfang Que1, Fuda Yu1, Jihuai Wu1
1Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Institute of Materials Physical Chemistry, Huaqiao University, Xiamen 361021, China.
在零度以下的温度下,离子电池 (SIB) 中的电压振荡是由阴极相变引起的. 使用diglyme溶剂可以消除这个问题,在低温下提高性能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 电压振荡是离子电池 (SIB) 在零度以下温度下常见但不太了解的问题.
- 这种现象显著降低了传统电解质中Na3V2(PO4) 3 (NVP) 阴极等材料的性能.
研究的目的:
- 为了研究电压振荡,NVP阴极的结构变化和零度以下温度下的电解质特性之间的相关性.
- 确定电压振荡的根本原因,并提出减轻它的策略.
主要方法:
- 理论上的计算理论上的计算.
- 在现场和现场特征表征技术.
- 交叉电化学实验 交叉电化学实验
主要成果:
- 在-20°C的碳酸 (PC) /乙烯碳酸 (EC) 电解质中NVP阴极的局部相变被确定为电压振荡的原因.
- 在NVP-PC/EC系统中,高解溶能障碍导致交换电流密度低,加剧相位转换和振荡.
- 引入具有较低Na-溶剂结合能量的diglyme溶剂,有效消除了电压振荡.
结论:
- 该研究阐明了在零下条件下SIB中电压振荡背后的机制.
- 迪格莱姆溶剂显著提高了NVP阴极性能,在-20°C时达到98.3%的容量保留,在-40°C时达到75.3%.
- 这项研究强调了解决电压振荡对于可靠的低温电池运行的重要性.
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