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Updated: Jun 28, 2025

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

Published on: February 7, 2019

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连接螺旋梯类型的芳香乳液

Huidong Xie1,2, Zuo Xiao1,2, Yixiao Song1,2

  • 1Center for Excellence in Nanoscience, Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China.

Journal of the American Chemical Society
|April 16, 2024
PubMed
概括

研究人员合成了具有独特螺旋结构的新型结合芳香乳酸. 这些化合物表现出客体适应性托管能力,特别是对于富勒烯,并显示出作为循环偏光发射器的潜力.

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group...
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