在水化和碳化之前和之后,从木灰中出重金属
Lisbeth M Ottosen1, Nina M Sigvardsen2
1DTU Sustain, Department of Environmental and Resource Engineering, Technical University of Denmark, 2800, Lyngby, Denmark. limo@dtu.dk.
Environmental science and pollution research international
|April 16, 2024
概括
木灰 (WFAs) 可以浸出重金属. 老化WFAs通过将它们纳入新的矿物相来减少大多数金属的漏,但漏仍然是环境安全的一个问题.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 地质化学 地质化学
背景情况:
- 木灰,特别是木灰 (WFA),被考虑用于土壤修改和建筑材料等用途.
- 从WFAs中潜在的重金属漏会给环境带来风险.
- 了解影响重金属流动性的WFA特征对于安全回收至关重要.
研究的目的:
- 调查影响WFAs重金属漏的因素.
- 评估老化过程 (水合和碳化) 对重金属漏的影响.
- 为了确定与重金属流动性相关的特定WFA特征.
主要方法:
- 分析了八个不同的WFA.
- 化学建模以将WFA特征与重金属漏相关联.
- 在环境空气中老化过程中监测WFA pH,导电性和重金属漏的变化.
主要成果:
- 溶解Cr和Zn与和硫酸盐度相关,与可溶性K2和SO4相关.
- 随着年龄的增长,WFA的pH和导电性下降,这表明新阶段的形成.
- 经过老化后,Cd,Cu,Ni,Pb和大多数Zn的浸出显著减少,变得无法测量.
- 泄漏减少,但仍可测量,这表明不完全固定或水溶性分数.
结论:
- 老化使WFAs中的大多数重金属停滞不前,进入新形成的矿物阶段.
- 由于潜在的毒性 (Cr(IV)) 导致老化WFA中的持续浸出,因此需要进一步调查.
- 对于安全和可持续的回收应用,需要更好地了解WFA化学.
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