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Updated: Jun 28, 2025

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在缓慢压缩时重新排列一个堵塞的二维乳液的缓慢压缩

Xin Du1, Eric R Weeks2

  • 1Department of Physics and Astronomy, Widener University, Chester, Pennsylvania 19013, USA.

Physical review. E
|April 18, 2024
PubMed
概括

在堵塞的无形材料中,局部结构会影响粒子运动. 带有空隙的异质区域促进滴滴重排,这是这些系统中的一个关键动态.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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