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化碳作为水性初级电池的高性能阴极
Congping Xu1,2,3, Liang Zhang4, Fupeng Liu1
1Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology Ganzhou 341000 Jiangxi China fupengliu@126.com.
RSC advances
|April 18, 2024
概括
化碳 (CFx) 显示出作为水性电池的阴极的承诺. CF0.85提供了503 mA hg-1的高容量,证明了其在这个系统中的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 碳 (CFx) 在电池中被认为具有高能量密度.
- 其他电池系统中CFx的研究有限,特别是水性电池系统.
研究的目的:
- 研究CFx作为水性电池的阴极材料.
- 探索F/C比对电化学性能的影响.
- 阐明Zn/CFx系统中的放电机制.
主要方法:
- 对具有不同F/C比的Zn/CFx细胞进行系统的电化学评估.
- 不同水性离子电解质的性能测试.
- 使用XPS,XRD,SEM和EDS分析阐明机制.
主要成果:
- CF0.85表现出卓越的性能,排放能力为503 mA hg-1,能量密度为388 W h kg-1,温度为25°C.
- CF0.85在0°C (460 mA hg-1) 和50°C (550 mA hg-1) 时表现出良好的容量保留.
- 性能受到F/C比率的显著影响,表现优于CF0.70,CF0.95,CF1.10.
结论:
- CFx是水性初级电池的可行的阴极材料.
- F/C比是优化性能的一个关键参数.
- 这项研究强调了CFx在下一代水性能源存储方面的潜力.
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