通过挥发性成分的蒸发,增强光吸收和大气棕色碳的高粘度
Diego Calderon-Arrieta1, Ana C Morales1, Anusha Priyadarshani Silva Hettiyadura1
1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
Environmental science & technology
|April 18, 2024
概括
生物质燃烧产生棕色碳 (BrC) 气溶,随着大气老化通过蒸发变黑. 这项研究量化了降低挥发率如何增加BrC的光吸收,并影响大气模型.
科学领域:
- 大气化学 大气化学
- 生物质燃烧排放的排放量
- 气溶科学 气溶科学
背景情况:
- 来自生物质燃烧的棕色碳 (BrC) 影响地球的辐射平衡.
- 了解BrC衰老过程对于气候建模至关重要.
研究的目的:
- 为了量化 BrC 在大气老化过程中增加的光吸收.
- 为了研究导致BrC变黑的化学和物理变化.
主要方法:
- 收集的木材热解烟雾作为生物质燃烧BrC的代理.
- 通过热蒸发处理样品以模拟老化.
- 使用HPLC-DAD-HRMS分析了化学成分和光吸收.
- 测量和蒸汽压力和粘度的变化.
主要成果:
- 在模拟老化 (蒸发) 过程中,BrC的光吸收量翻了一番.
- 吸收安格斯特罗姆指数下降,表明光谱依赖性较弱.
- 在405nm时,质量吸收系数显著增加.
- 衰老导致氧化化合物的耗尽,并保留了较大,较少的极性化合物.
- 和蒸汽压力下降,粘度大大增加.
结论:
- 非反应性蒸发显著使BrC气溶变暗.
- 这些物理和化学变化增强了BrC对气候的影响.
- 这些发现将改进大气和化学物质运输模型.
更多相关视频
13:27Exploring the Effects of Atmospheric Forcings on Evaporation: Experimental Integration of the Atmospheric Boundary Layer and Shallow Subsurface
Published on: June 8, 2015
8.7K
08:12Characterization, Quantification and Compound-specific Isotopic Analysis of Pyrogenic Carbon Using Benzene Polycarboxylic Acids BPCA
Published on: May 16, 2016
15.5K
相关概念视频
Volatilization
385
Volatilization gravimetry is an analytical technique that measures the mass lost due to the volatilization of the substance. This technique is used to estimate the amount of volatile material in a sample. To perform this method, heat a known amount of the sample to a high temperature in a crucible or other suitable vessel. The volatile substance in the sample evaporates, and the vapor is completely expelled from the crucible either by heating the sample or bubbling a stream of inert gas through...
385
The Carbon Cycle
37.4K
Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
37.4K
Vaporization
34.6K
The physical form of a substance changes by changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. For vaporization to occur, kinetic energy must be greater than the intermolecular forces that keep molecules bonded. The amount of energy needed to vaporize a quantity of liquid at a given pressure and a constant temperature is called the heat of vaporization. When...
34.6K
Bioremediation
18.3K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.3K
Adaptations that Reduce Water Loss
25.5K
Though evaporation from plant leaves drives transpiration, it also results in loss of water. Because water is critical for photosynthetic reactions and other cellular processes, evolutionary pressures on plants in different environments have driven the acquisition of adaptations that reduce water loss.
25.5K
The Calvin Benson Cycle
4.5K
Ribulose 1,5- bisphosphate carboxylase/oxygenase (RuBisCo) is a critical enzyme that catalyzes carbon dioxide assimilation during photosynthesis. However, it is an inefficient enzyme, having an extremely slow catalytic rate. A typical enzyme can process about a thousand molecules per second; however, RuBisCo fixes only around three-carbon dioxides per second. Photosynthetic cells compensate for this slow rate by synthesizing very high amounts of RuBisCo, making it the most abundant single...
4.5K
