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Updated: Jun 28, 2025

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重新定义的离子关联常数对酸核化和生物矿物化产生了影响

David P McDonogh1, Julian D Gale2, Paolo Raiteri3

  • 1Institute of Inorganic Chemistry, Leibniz University Hannover, Callinstr. 9, 30167, Hannover, Germany.

Nature communications
|April 18, 2024
PubMed
概括

酸 (CaP) 规范得到了修订,显示酸,而不是酸,主导生物矿物化. 这一发现纠正了对了解骨和牙形成至关重要的长期热力学数据.

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
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When a substance such as sodium chloride is added to water, it dissolves, forming an aqueous solution. The extent of dissolution is called solubility. The process of dissolution can exist in equilibrium, just like other chemical processes. Solubility equilibria are also called precipitation equilibria because the process of solubility can be reversible. The reverse of the solubility process is called precipitation.
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