在有机太阳能电池中压缩分子包装的扩展非烯受体,以达到20%以上的效率
Yuandong Sun1, Liang Wang1, Chuanhang Guo1
1School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.
Journal of the American Chemical Society
|April 19, 2024
概括
一种新的非富勒因接受剂B6Cl通过优化分子包装来增强有机光伏. 这提高了充电传输,减少了能量损失,提高了设备的整体效率.
科学领域:
- 材料科学
- 有机电子
- 太阳能发电
背景情况:
- 有机光伏 (OPV) 面临的挑战是平衡高效的电荷传输与最大限度地减少非辐射重组.
- 有机半导体的聚合诱导的光度灭阻碍了OPV的性能.
研究的目的:
- 引入一种新的π扩展非烯受体 (NFA),B6Cl,以克服OPV的性能限制.
- 研究B6Cl对宿主受体的分子包装和形态的影响.
主要方法:
- π扩展非烯受体B6Cl的设计和合成.
- 将少量的B6Cl纳入OPV系统 (PM6:L8-BO和D18:L8-BO).
- 高能X射线散射测量以分析分子包装和形态.
主要成果:
- 添加B6Cl (0.5-1%重量) 的压缩分子包装L8-BO,缩短π-π堆叠距离至3.50 Å.
- 观察到有序的链包装,抑制非辐射能量损失.
- 在短路电流 (JSC),充电因子 (FF) 和开路电压 (VOC) 中实现了同时的改进.
结论:
- B6Cl有效地优化了OPV的形态,从而提高了电荷传输和减少了重组.
- 对于PM6:L8-BO和D18:L8-BO,最大功率转换效率分别提高到19.8%和20.2%.
- 在提高各种聚合物:NFA有机光伏设备的性能方面,B6Cl具有广泛的应用性.
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