在氧导电多变体金属有机框架中与热力学驱动的电子传输相连的扩散电子传输
Jingguo Li1,2, Amol Kumar1, Sascha Ott1,2
1Department of Chemistry─Ångström Laboratory, Uppsala University, Box 523, 75120 Uppsala, Sweden.
Journal of the American Chemical Society
|April 19, 2024
概括
研究人员开发了混合链接器金属有机框架 (MOF),以了解电子传输. 他们确定了两个电子传播模式,揭示了对能量储存和催化应用至关重要的氧化还原导电性的洞察力.
科学领域:
- 材料科学
- 电化学
- 纳米技术
背景情况:
- 反氧导体金属有机框架 (MOF) 对于储能,电子和催化是必不可少的.
- 了解MOF中的电荷传播是优化其性能的关键.
研究的目的:
- 研究MOF中的扩散电子跳转传输和氧化还原导电性.
- 在混合连接器MOF中阐明电荷传播机制.
主要方法:
- 使用 pyromellitic diimide bis-pyrazolate (PMDI) 和 naphthalene diimide bis-pyrazolate (NDI) 结合剂构建的混合结合剂MOF.
- 在氧化 (FTO) 上生长晶体薄膜.
- 使用循环电压测量,光谱测量和脉冲阶段电位光谱电压测量.
主要成果:
- 在混合链体MOF中解决了四个不同的氧化还原事件和五个离散的氧化还原状态.
- 确定了两种电子传播模式:内链接器跳跃和内链接器电子转移.
- 根据连接器距离观察到四个独特的氧化还原导电特性.
结论:
- 混合链式MOF具有可调节的氧化还原特性和独特的电荷传输路径.
- 电荷传输机制受到连接器类型和空间布局的影响.
- 这项工作推动了电催化和储能应用的MOF设计.
相关概念视频
Electron Transport Chain: Complex III and IV
7.4K
During the electron transport chain, electrons from NADH and FADH2 are first transferred to complexes I and II, respectively. These two complexes then transfer the electrons to ubiquinol, which carries them further to complex III. Complex III passes the electrons across the intermembrane space to Cyt c, which carries them further to complex IV. Complex IV donates electrons to oxygen and reduces it to water. As electrons pass through complexes I, III, and IV, the energy released aids the pumping...
7.4K
Redox Equilibria: Overview
564
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
564
Electron Transport Chain: Complex I and II
13.1K
The mitochondrial electron transport chain (ETC) is the main energy generation system in the eukaryotic cells. However, mitochondria also produce cytotoxic reactive oxygen species (ROS) due to the large electron flow during oxidative phosphorylation. While Complex I is one of the primary sources of superoxide radicals, ROS production by Complex II is uncommon and may only be observed in cancer cells with mutated complexes.
ROS generation is regulated and maintained at moderate levels necessary...
ROS generation is regulated and maintained at moderate levels necessary...
13.1K
Oxidation and Reduction of Organic Molecules
6.5K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
6.5K
The Supercomplexes in the Crista Membrane
2.5K
The mitochondrial cristae membrane is the primary site for the oxidative phosphorylation (OXPHOS) process of energy conversion mediated through respiratory complexes I to V. These complexes have been widely studied for decades, and it has been proven that they form supramolecular structures called respiratory supercomplexes (SC). These higher-order complexes may be crucial in maintaining the biochemical structure and improving the physiological activity of the individual complexes while...
2.5K
Balancing Redox Equations
52.1K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
52.1K


